Proposed strategy to correlate thermoelectric properties via imaging (https://doi.org/10.1002/adma.202302777) with analysis of grain boundary structure and chemistry, to obtain high performance.
Thermoelectric (TE) devices are attractive for waste-heat energy harvesting, as well as for cooling and heating applications due to their versatile, reliable, and refrigerant-free operation. A particularly promising application of TEs is device-level heat management, which is increasingly critical for achieving high performance and efficiency in technologies such as batteries, advanced electronics, and hardware for computing and datacenters. The cooling performance of TE devices is linked to the materials figure of merit, zT, which is proportional to the ratio of electrical (σ) to thermal conductivity (κ). State-of-the-art TE materials typically reach zT ~ 1.1–1.4 near 300 K. Achieving reproducible zTs ~1.3–1.7 would render TEs technologically competitive, thus enabling their integration into heat management systems.
PhD Objective and methodology
In this PhD thesis, we propose to achieve high zT via advanced grain-boundary engineering. GBs offer a compelling and novel material design space. In fact, recent literature suggests that: (i) GBs behave as ‘phases’ and can thus exist in multiple forms, with different local chemistry and structural arrangements; (ii) the type of GBs can have major impact on its thermal and electrical transport. TE research typically relies on macroscale measurements of κ and σ, incapable of distinguishing the role of individual GBs. As such, what GB types are beneficial for TEs remains unclear. We recently demonstrated that measuring κ for individual GBs is possible (Fig 1). Measuring the σ of individual GBs was also recently shown in metals. However, these have never been put together: what GBs possess higher σ/κ remains unknown, though pivotal for rationally pursuing GB engineering in TEs.
The PhD researcher will develop a strong experimental background and will focus on (i) TE material synthesis and characterization, including with thermal conductivity imaging (FDTR thermoreflectance), local electrical measurements, and electron microscopy; (ii) data analysis and theoretical/analytical interpretation of results; (iii) TE device assembly and optimization. Outcomes will include publications in international scientific journals as well as presentations at national and international conferences. The candidate will develop an attractive profile for a career in industry R&D, as well as academia.
Working environment:
This project is one of the key milestones of HEAT FIS-3 Starting Grant, and will be carried out at the Energy and Materials Laboratory. Electron microscopy investigations will be carried out in collaboration with the Max Planck Institute for Sustainable Materials, in Germany, where the candidate will have the opportunity of spending a research stay.
Candidate profile:
Student with a Master degree in Materials Science, Physics, Engineering, or related (to be acquired by 31st October 2026).
Beginning of PhD contract:
1st November 2026.
Contact: Interested candidates are invited to send their CV and Master’s transcript to Dr. Eleonora Isotta: eleonora.isotta@gmail.com
Funded by:
Fondo Italiano per la Scienza FIS-3 Starting Grant – Project ‘HEAT’, FIS-2024-05016
Finanziata con il contributo del Ministero dell’Università e della ricerca ai sensi del D.D. n.18010 del 12 novembre 2025 – BANDO FIS 3.